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![]() ![]() PROJECT provides a professional approach to portfolio and project management.MINDMAP is essential to strategic planning, knowledge, and team management.DIAGRAM professional-quality graphic solutions of all sorts for all businesses.PROJECT can plan project schedules, calculate expenses, track task execution, manage resource allocations, and set communication processes between team members through to-do lists, comprehensive reports, and compatibility with MS Project and MS Excel.Powerful presentation capabilities and seamless integration with MS Office and other mind map apps transform MINDMAP into a tremendous analytical and planning tool in a shared visual environment.DIAGRAM is the only professional alternative to MS Visio on the Mac and PC, the benchmark in business graphics in the last twenty years. ![]() Live Objects technology provides a unique tool for drawing live interactive diagrams and dashboards.To guide you through Solutions, we provide the ConceptDraw STORE application that identifies what you have in your operating system and what is available from both a product and a solution perspective, assisting in the trials’ installations and product compatibility. The collection of Solutions contains a wide range of professional free and paid graphics solutions and learning materials on how to use them with the ConceptDraw products. ConceptDraw OFFICE v9 is essential for brainstorming sessions and creating diagrams, schematics, mind maps, project plans, dashboards, presentations, and other business visualizations. The suite combines business diagramming, mind mapping, and project management software. It includes three software products integrated with unique data exchange technology. Overview of ConceptDraw OfficeĬonceptDraw OFFICE v9 is a powerful software suite especially tailored for business managers of all types but also designed to be comprehensive for whatever business task you are working on. Free Download ConceptDraw Office for Windows is a powerful software suite tailored for business managers of all types and designed to be comprehensive for whatever business task you are working on. ![]() ![]() Since hail can cause the rainfall estimates to be higher than what is actually occurring, steps are taken to prevent these high dBZ values from being converted to rainfall. Hail is a good reflector of energy and will return very high dBZ values. Radar Current Weather Rivers & Lakes Satellite Forecast Maps Hour by Hour Forecast Winter Weather Graphical. These values are estimates of the rainfall per hour, updated each volume scan, with rainfall accumulated over time. Depending on the type of weather occurring and the area of the U.S., forecasters use a set of rainrates which are associated to the dBZ values. The higher the dBZ, the stronger the rainrate. Typically, light rain is occurring when the dBZ value reaches 20. ![]() Wind direction is W at 7 mph with visibility of 10.00 mi. 21 hours ago &0183 &32 Live Doppler 13 Forecast 4:30 p.m. The scale of dBZ values is also related to the intensity of rainfall. Pomona Police Dept Doppler Radar Current Conditions: Clear, the temperature is 59☏, humidity 55. NA 64F 18C More Information: Local Forecast Office More Local Wx 3 Day History Mobile Weather Hourly Weather Forecast Extended Forecast for Pomona CA. The value of the dBZ depends upon the mode the radar is in at the time the image was created. See the latest Arizona Doppler radar weather map including areas of rain, snow and ice. Wind direction is NE at 5 mph with visibility of 10.00 mi. Notice the color on each scale remains the same in both operational modes, only the values change. Pomona Park Doppler Radar Loop Current Conditions: Clear, the temperature is 73☏, humidity 83. The other scale (near left) represents dBZ values when the radar is in precipitation mode (dBZ values from 5 to 75). One scale (far left) represents dBZ values when the radar is in clear air mode (dBZ values from -28 to +28). Each reflectivity image you see includes one of two color scales. The dBZ values increase as the strength of the signal returned to the radar increases. So, a more convenient number for calculations and comparison, a decibel (or logarithmic) scale (dBZ), is used. Reflectivity (designated by the letter Z) covers a wide range of signals (from very weak to very strong). "Reflectivity" is the amount of transmitted power returned to the radar receiver. North America > United States of America > New York > Pomona Radar. Wind direction is NW at 10 mph with visibility of 5.00 mi. The colors are the different echo intensities (reflectivity) measured in dBZ (decibels of Z) during each elevation scan. Satellite and Doppler radar images for Pomona, NY. Pomona Lake Doppler Radar Loop Current Conditions: Light Snow, the temperature is 36F, humidity 93. ![]() ![]() ![]() In summary, the estimated total annual price of adopting a white cockatoo varies considerably depending on the breeder or retailer you buy it from and the lifestyle you provide for it once it has arrived in your home however, it is generally estimated that the average cost to swim and maintain a pet bird such as the white cockatoo can range from $XNUMX to $XNUMX annually for a middle-aged specimen. Veterinary care: always make sure you have enough funds to cover unforeseen veterinary expenses at the end of the month Recommended standards are at least to set aside about ten percent of the total annual cost for your pet's care (including vaccinations and annual exams suggested by the veterinarian). Toys: Cockatoos need interactive toys designed specifically for them they are available in many retail stores or online for around $10-$20 each (depending on the type). The average cost per month is generally between $20-$30 (depending on the type and quantity). Food: Proper nutrition is essential to keep your pet healthy however, specialized cockatiel foods are relatively expensive compared to other types of common household pets. In addition to the initial price of the pet, there are other costs related to the daily care of the pet that you should consider before buying it. Adult cockatoos command higher prices, with prices averaging between $500-$1000 or more depending on the breeder or retailer where you buy the bird. The average price for a young bird is generally between $50-$150, but prices can vary significantly depending on the breeder or retailer where you buy the bird. The initial expenses for purchasing a white cockatoo include the price of the bird itself, as well as expenses related to its transportation and temporary housing until it reaches its new home. If you are considering adopting a white cockatoo, it is important that you understand the costs associated with keeping it before making your final decision. These birds have unique personalities and can make great pets if given proper care. White Cockatoos are beautiful and popular birds characterized by their brilliant white plumage and vivid wing colors. Prices can range from around $50 for a young cockatoo to over $1000 for an adult bird. The price of a white cockatoo depends on several factors, such as age, size, and breed. 4 How much does a molucca cockatoo cost?.2 How much does a papillera cockatoo cost?. ![]() Enjoy Sudoku online or in offline mode!įor support please contact us at or visit RazzlePuzzles. You can play Sudoku by Razzle Puzzles on your phone and tablet. Track your best and average solve times over history with our stats tracker. Our Sudoku game also saves your uncompleted puzzles so you can come back and finish them whenever you want! Work your way up through four levels of difficulty: easy, normal, hard and expert Sudoku. This Sudoku game offers numerous features to help you solve the puzzles including cell candidate tracking, unlimited undo moves and a “check” feature that lets you know how you’re doing. Challenge your Sudoku solving skills with our hard Sudoku puzzles! While solving it’s good to keep in mind that a number cannot appear more than once in a given row, column or 3x3 box. Fill in the grid such that every row, column and 3x3 box contains all of the numbers from 1 to 9. If you like logic, number-based puzzles, you will love these classic Sudoku puzzles!Įvery Sudoku puzzle has a unique solution that can be reached logically without guessing. Sudoku.Enjoy Sudoku, with thousands of free Sudoku puzzles on one of the best Sudoku games in the app store. The game offers many handy features to sudoku lovers like game hints, automatic control, and highlighted copies. Players can play by choosing the level they want. I finally got comfortable with the expert level puzzles and I decided to test out the Evil difficulty. is a game that people of all levels can enjoy and one of the best logic games for iPhone. Best Sudoku app Giving it 4 stars because the evil difficulty seems to be broken. Every cell is part of a cage, indicated by dotted lines. How to play: Each Sudoku has only one true solution. Game lovers can effortlessly get rid of the stress of the day and keep their brains active with . Download the App Contact Us 2023 The New York Times Company . With our Sudoku puzzles app, you can not only enjoy killer sudoku games anytime anywhere, but also learn Sudoku techniques from it. The game has thousands of classic sudoku puzzles and includes daily tasks. – Number Games is one of the games in which you will have fun while training your brain. Price: Free/In-App Purchase: $4.99 Sudokucom Number Games You can solve the games on your mobile phone, tablet or computer. The UI is simple, and you’ll easily find out how it works. Smarter Sudoku brings daily online Sudoku puzzles for free. Plus, there are such types as Jigsaw, Nonomino, Diagonal, and more. It features several types of grids: 12×12 and 16×16, and you can select the one you like most. There are 840 various levels to complete in the game.Īlso Read: The 9 Best Card Games for iPhone This app covers all the popular variations of the sudoku game. Are you looking for something more than just classic Sudoku If so, then this Android app is just what you need. You can go from easiest to hardest in all the different settings offered. On our website, you will find an endless supply of Sudoku puzzles, from the easiest to the most difficult. In Cross Fingers, players will try to put together solid pieces. Best sudoku app out there The options alone make this app the best. Welcome to the best Sudoku website in the world. Price: Free/In-App Purchase: Up to $29.99 Cross FingersĬross Fingers is an unusual game that features a massive tangram puzzle that will improve your dexterity. Browse Brain It On’s website to learn more details about the game.īrain It On! on the App Store Cross Fingers Puzzazz is the best Sudoku puzzle app for iPad, iPhone. It has tutorials on the techniques, good hints, and the difficulty is broken up. Puzzazz is the best way to solve Sudoku puzzles, including a free hand-crafted Sudoku puzzle every day. You can also create puzzles where you know what techniques will be required to solve it. Fun The best sudoku apps you can use in 2023 (top 4) JIf youre wanting to keep your brain active, playing a challenging game is a great way to do just that. The app is free with available in-app purchases of hint packages from 2.99 to 29.99. Sudoku World is loaded with options that make it a great choice for players, no matter what their level of experience. Each puzzle in the game has multiple solutions, and players aim to find the best solution. You can set up training modes where you know exactly what technique is going to be the next step in the solution. The app supports various game achievements and leaderboards, so you can compare your scores and times with other players. It features more than 5000 types of Sudoku puzzles and also includes 4 different difficulty levels. It also happens to be one of the Editor’s choice. The game allows players to fight with their friends. app on the Play Store is the most popular Sudoku app for Android mobiles. In physics puzzles, players will draw shapes to solve the puzzle. Brain It On is a game with tricky and challenging puzzles that will challenge your brain and deserves to be among the best logic games for iPhone. ![]() The Enterprise and Picard pay a visit to the station, and Sisko blames Picard for his wifes death. ![]() The Federation takes over the abandoned outpost Terok Nor, renaming it Deep Space Nine, with Benjamin Sisko in command. As panicked, narrative ass-saving measures go, it's a 7. 2369 (TNG Season 6, DS9 Season 1) The Cardassians end their occupation of Bajor. A decade after last playing their characters in the live-action TV series, the first of the Star Trek films was released with. As such, the Discovery more or less deleted itself from existence. set 2273 2293 (released 1979 1991) star trek films 1-6. As such, at the end of the second season of "Discovery," the ship was thrown almost 1,000 years into the future in order to outrun an insidious computer intelligence that would spread throughout the galaxy if knowledge of it was passed around. Star Trek: Deep Space Nine Season 1 The Complete Series. Publication Order of Star Trek: Deep Space Nine (Young Adult) Books The Star Ghost Stowaways Prisoners of Peace The Pet Arcade Field Trip Gypsy World. The show's writers also needed to come up with an organic reason why a ship that can teleport - a technology that would have fundamentally changed the world of "Star Trek" - was never mentioned in any of the "Trek" shows made from 1966 until 2017. Episode 12 in the Animated Bible series that shows the story of Christs burial. There were a lot - and I mean a LOT - of narrative excuses as to why the high-tech Discovery (realized with late-2010s special effects) didn't match the boxier, monochromatic world of "The Cage." The charming-yet-wily Cardassian tailor (and spy) called Deep Space Nine his home, but. Hes also part of actor Andrew Robinson in a unique way. Publication Order of Star Trek: Enterprise: Rise Of The Federation Books. Enterprise while it was still being captained by Christopher Pike (now played by Anson Mount), putting the events of "Discovery" immediately after the original pilot. Elim Garak isnt special to 'Star Trek' fans alone. ![]() After surviving the Klingon war, the Discovery teamed up with the U.S.S. ![]() At the Millenium Stadium in Cardiff, Wales, Knight joined such performers as Jennifer Hudson, Beyonce, and Smokey Robinson in a tribute to the legendary King of Pop in a concert event called “Michael Forever.” Following that, Knight was honored with a “Legend Award” alongside fellow recipients Earth, Wind & Fire on the BET broadcast of the 3rd annual Soul Train Awards, hosted by Cedric the Entertainer. The year of 2011 was a year of much recognition as Knight was both honoring and being honored, first at a Michael Jackson tribute concert, and then at the 2011 Soul Train Awards. She joined the cast of ABC’s hit reality competition “Dancing with the Stars” for season 14, partnering with Tristan MacManus. No stranger to performing and light choreography over the course of her career, Knight raised the stakes when she put on her dancing shoes in the spring of 2012. Fresh and Michael Bivins, the legendary songstress gave guidance to contestants as they took the stage with the hope to jumpstart their career in the entertainment industry. Henson.Īlso on the small screen, Knight recently shared her musical expertise on the second season of Centric’s original series “Apollo Live.” Joining judges Doug E. In the New Year she will guest on Lee Daniels and FOX TV’s new series “Empire” opposite Terrence Howard and Taraji P. Henson and fellow Grammy winner Cliff “Method Man” Smith. In the story about two lovers as they journey through life, love and family, Knight stars alongside Oscar-nominee Taraji P. Last month, Knight returned to the small screen in the Lifetime original movie “Seasons of Love”. “Another Journey” enjoyed success from the hit “I Who Have Nothing” as well as the up- tempo track “Settle,” produced by Randy Jackson, with whom she previously collaborated with on her Grammy-winning album, “At Last.” Knight also enjoyed the success of her song “You and I Ain’t Nothin’ No More” which appeared over the end credits of the critically-acclaimed Lee Daniels film THE BUTLER. Knight is a two-time Grammy winner in the gospel category, and “Where My Heart Belongs” dropped on September 9th from Deseret Book, and recently won an NAACP Image Award for “Outstanding Gospel Album.” In her first effort since 2013’s “Another Journey” – Knight’s 8th solo effort – this summer marked the release of “Where My Heart Belongs”, a new inspiration gospel album. This seven-time Grammy winner has enjoyed #1 hits in Pop, Gospel, R&B and Adult Contemporary, and has triumphed in film, television and live performance. Very few singers over the last fifty years have matched her unassailable artistry. The great ones endure, and Gladys Knight has long been one of the greatest. ![]()
![]() Since we are a young organization, the designer will also get the opportunity to play a cross-functional role and contribute to the design, curation, and creation of digital content for social media and marketing purposes.Ĭonceptualise and execute illustration or photo-based social media creatives on the defined creative strategy and approachĬonceptualise and execute digital marketing collaterals such as banners, emailers, etc. The designer will work closely with the design lead and product manager to execute several visual aspects of the product, focusing on typography, iconography, and motion graphics. We believe a Graphic Designer will play an integral role in enhancing our overall product and brand experience. We are looking to add a Graphic Designer to our growing team striving to make a better place for both readers and writers on the platform. Some of our angel investors include Naval Ravikant, Guillermo Rauch, Salil Deshpande, and Des Traynor. We are backed by investors such as Accel India, Sequoia Capital India's Surge, Sierra Capital, and Salesforce Ventures. We are a small, passionate team who love solving bigger challenges. The user base has increased from zero to millions in just over a year. The platform is growing at 20% MoM on various KPIs on an average - purely organic word of mouth. ![]() At its core, Hashnode allows writers to share their knowledge easily with the tech community without the hassle of building a blog from scratch and managing it. Hashnode is one of the fastest-growing knowledge-sharing platforms for developers, engineers, and people in tech. ![]() The theoretical defect-free crystal structure of the Cu-Co DMC is shown in Fig. Depending on the valences of the metal ions, n can be 4, 6, or 8, with 6 being the most common for materials crystallizing in the cubic phase. M 1 typically is a divalent metal ( v = 2), like Zn(II) or Cu(II), and M 2 is a trivalent metal ( u = 3), like Co(III) or Fe(III) however, other u- v combinations are also possible, such as 1–1, 4–3 20. DMCs have the general formula M 1 u v (sometimes expressed as M 1-M 2 DMC for simplicity). Inspired by these reports we envisioned a system that includes all the attractive features of the metal-catalyzed oxidative coupling, while also introducing the benefits of a heterogeneously catalyzed system.ĭouble metal cyanides (DMCs) are coordination polymers in which two different metals are linked through a cyanide group (C≡N). ![]() Furthermore, similar homogeneously catalyzed aerobic oxidative cross-coupling systems for P-N bond formation have been investigated, with Cu emerging as the metal of choice for this transformation 18, 19. 17 proposed a mild and atom-efficient synthesis of phosphoramidates starting from phosphites and amines using CuI as catalyst however, this approach suffered from the formation of oxidation side products 17. In this sense, homogeneous Cu salts have shown very promising results 15, 16. While these methods are well-established, they all suffer from either dependency on non-desired precursors or poor atom/step economy.Ī more environmentally friendly approach to the phosphoramidate synthesis is the use of metals for the aerobic oxidative coupling of phosphites and amines. 1d) 13 and the ZnI 2 triggered catalytic oxidative coupling of P(O)-H compounds and amines using an organic oxidant (Fig. 1c) 11, the direct electrochemical oxidation of phosphites and amines 12, the selenite-catalyzed Atherton–Todd-like reaction of phosphites and amines (Fig. ![]() More recent alternatives for phosphoramidate synthesis include the formation of phosphoryl azide precursors (Fig. However, the use of stoichiometric amounts of CCl 4 is highly undesired from an industrial point of view. For example, in the Atherton–Todd reaction a phosphoryl chloride is generated by the halogenation of phosphites using CCl 4 as a chlorine donor (Fig. An alternative to the direct use of halogenated phosphor substrates can be their in situ formation. These straightforward methodologies often use highly toxic reagents, such as the phosphoryl halide itself, and unpractical conditions, such as pre-cooling and fuming reactions 8, 9. Such is the interest in these products that several synthetic methodologies to obtain them have been developed during the last decade 3, 4, 5, 6, 7.Įarly strategies for phosphoramidate synthesis relied on the direct reaction of amines with the corresponding phosphoryl halides (Fig. The phosphoramidate moiety is present in a wide variety of high-value natural and synthetic compounds, ranging from biologically active natural products, such as nucleotides 1, to ligands in metal catalysis and environmentally friendly flame retardant additives 2. ![]() Preliminary mechanism studies suggest that the reaction proceeds by a continuous change in the oxidation state of the Cu metal, induced by a O 2/I − redox cycle. While the detailed study of the catalyst structure and of the metal centers by PXRD, FTIR, EXAFS and XANES revealed changes in their coordination environment, the catalyst maintained its high activity for at least 5 consecutive iterations of the reaction. This strategy successfully provides an efficient, environmentally friendly alternative to the synthesis of these valuable compounds in high yields and it is, to the best of our knowledge, the first heterogeneous approach to this protocol. Here we report the coupling of phosphites and amines promoted by a Cu 3 2-based double metal cyanide heterogeneous catalyst using I 2 as additive for the synthesis of phosphoramidates. Conventional approaches to their synthesis make use of toxic chlorinated reagents and intermediates, which are sought to be avoided at an industrial scale. Phosphoramidates are common and widespread backbones of a great variety of fine chemicals, pharmaceuticals, additives and natural products. ![]() "Turns of wire per unit length" is the reciprocal of the conductor diameter it is therefore an upper limit for wire wound in the form of a helix (see solenoid), based on uninsulated wire.Understanding wire gauge (thickness) is important when buying craft wire or beading wire, or items made from wire such as jump rings, head pins, earring hooks, and other findings. The table below assumes DC, or AC frequencies equal to or less than 60 Hz, and does not take skin effect into account. Fusing current (melting wire) is estimated based on 25 ☌ (77 ☏) ambient temperature. Stranded wires are calculated by calculating the equivalent cross sectional copper area. The diameter information in the table applies to solid wires. The table below shows various data including both the resistance of the various wire gauges and the allowable current ( ampacity) based on a copper conductor with plastic insulation. An approximation for the resistance of copper wire may be expressed as follows:Īpproximate resistance of copper wire : 27 AWG.A solid round 18 AWG wire is about 1 mm in diameter.For the same cross section, aluminum wire has a conductivity of approximately 61% of copper, so an aluminum wire has nearly the same resistance as a copper wire smaller by 2 AWG sizes, which has 62.9% of the area.A decrease of ten gauge numbers, for example from No. 12 to No. 2, multiplies the area and weight by approximately 10, and reduces the electrical resistance (and increases the conductance) by a factor of approximately 10. ![]() No. 2 AWG is about twice the diameter of No. 8 AWG.) This quadruples the cross-sectional area and the conductance. When the diameter of a wire is doubled, the AWG will decrease by 6.two No. 14 AWG wires have about the same cross-sectional area as a single No. 11 AWG wire.) This doubles the conductance. When the cross-sectional area of a wire is doubled, the AWG will decrease by 3.The sixth power of 39√ 92 is very close to 2, which leads to the following rules of thumb: For an m/0 AWG wire, use n = −( m − 1) = 1 − m in the above formulas. Sizes with multiple zeros are successively larger than No. 0 and can be denoted using " number of zeros/0", for example 4/. ASTM B258-02 also dictates that wire diameters should be tabulated with no more than 4 significant figures, with a resolution of no more than 0.0001 inches (0.1 mils) for wires larger than No. 44 AWG, and 0.00001 inches (0.01 mils) for wires No. 45 AWG and smaller. The standard ASTM B258-02 (2008), Standard Specification for Standard Nominal Diameters and Cross-Sectional Areas of AWG Sizes of Solid Round Wires Used as Electrical Conductors, defines the ratio between successive sizes to be the 39th root of 92, or approximately 1.1229322. Any two successive gauges (e.g., A and B ) have diameters whose ratio (dia. Because each successive gauge number increases cross sectional area by a constant multiple, diameters vary geometrically. The ratio of these diameters is 1:92, and there are 40 gauge sizes from No. 36 to No. 0000, or 39 steps. 36 AWG is 0.005 inches in diameter, and No. 0000 is 0.46 inches in diameter. Because there are also small gaps between the strands, a stranded wire will always have a slightly larger overall diameter than a solid wire with the same AWG.ĪWG is also commonly used to specify body piercing jewelry sizes (especially smaller sizes), even when the material is not metallic. The AWG of a stranded wire is determined by the cross-sectional area of the equivalent solid conductor. The AWG tables are for a single, solid and round conductor. Manufacturers of wire formerly had proprietary wire gauge systems the development of standardized wire gauges rationalized selection of wire for a particular purpose. ![]() Very fine wire (for example, 30 gauge) required more passes through the drawing dies than 0 gauge wire did. This gauge system originated in the number of drawing operations used to produce a given gauge of wire. Increasing gauge numbers denote decreasing wire diameters, which is similar to many other non-metric gauging systems such as British Standard Wire Gauge (SWG), but unlike IEC 60228, the metric wire-size standard used in most parts of the world. The cross-sectional area of each gauge is an important factor for determining its current-carrying ampacity. Dimensions of the wires are given in ASTM standard B 258. For other uses, see AWG (disambiguation).Īmerican Wire Gauge ( AWG), also known as the Brown & Sharpe wire gauge, is a logarithmic stepped standardized wire gauge system used since 1857, predominantly in North America, for the diameters of round, solid, nonferrous, electrically conducting wire. |
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